Yes.
It is set high for shipping and dealerships often miss lowering it before delivery. This happened with a Subaru I bought too, which was discovered a week later when the dealer tech person was giving us a tour of its various features… 😁
The pulley that the smudge is on is the belt tensioner and rides on the smooth side of the belt as is depicted in the routing diagram posted. The belt should be sitting in the grooves that are in the pulley to the right of the smudged one. I'm not familiar with this vehicle, but usually...
First question is how many porcupines have you strangled....?
Yes, something got in there and forced the belt off its track. It should be an easy matter to unload the belt tensioner and put it back in place once the foreign object is removed. The belt -might- be damaged, but probably not.